Statistical Thermodynamics of Polymer Solutions
نویسندگان
چکیده
منابع مشابه
Thermodynamics of Polymer Solutions
Most of the synthetic compounds are prepared and processed in the liquid state, i.e. in solution or in the molten state. Detailed knowledge on this state is therefore indispensable. In particular it is essential to know the limits of complete miscibility with a low molecular weight solvent as a function of temperature, pressure and composition. Furthermore it is often mandatory to be acquainted...
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We review the basic ideas and main results of our analysis of shear-induced effects in polymer solutions and blends. The analysis combines thermodynamic and hydrodynamic descriptions. The flow contribution to the free energy of the solution is described in the framework of extended irreversible thermodynamics, which relates the viscoelastic constitutive equations to a non-equilibrium entropy th...
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ژورنال
عنوان ژورنال: Macromolecules
سال: 1978
ISSN: 0024-9297,1520-5835
DOI: 10.1021/ma60066a017